This article details specifically the “X1” leather hardening technique I developed in late 2018 as an attempt to discover a method of creating hardened leather with the best balance of qualities including strength, cut resistance, pierce resistance, water resistance, and resistance to extremes of temperature, while minimizing brittleness and expense. The X1 method was the best of over 16 methods attempted. “X1” was the designation given to the first of several “cross” methods I attempted. Find the full article here. This hardening technique is perfect for a wide range of applications including drinking vessels, armor, tool sheaths, cases, and others.
We’ll begin with a full step-by-step “how-to” for achieving X1 hardened leather, followed by further notes to consider for leatherwork projects, and troubleshooting. This method has been tested only with vegetable-tanned cowhide, and I can’t vouch for results when using other leathers.
- Your leather project made from vegetable-tanned cowhide
- Stearic acid- enough to fully submerge your project. I buy mine here. (No affiliation)
- A metal container large enough to melt the stearic acid and immerse your project
- Hot plate or stove for melting stearic acid
- Thermometer- infrared is handy. Needs to measure molten stearic acid temps from 130F – 200F+
- Method to achieve 150F dry temperature- I use a toaster oven
- Rags or paper towel
Step 1: Ensure your leather project is absolutely bone dry.
I use a digital moisture meter to be sure. Any moisture remaining in the leather will cause warping and shriveling of the leather. Stitching, tooling, and dyeing should be done prior to hardening. Be aware any adhesives such as Barge, Weldwood, and others will fail completely during hardening, so all pieces should be well stitched together. The hardening process results in significant darkening, which tends to weather/lighten considerably and quickly with handling, and results in a beautiful color pattern of a somewhat darker shade of the dye used.
Step 2: Preheat your leather to 150F. I had surprising difficulty finding a way to hit 150F precisely, and currently use a toaster oven. I set the project in the oven with a remote probe thermometer on the “keep warm” setting, and nudge the dial back and forth until it settles into an acceptable range of +/- 5F of 150. Too hot, and the leather will begin to plasticize and prevent full saturation of the stearic acid. Too cool, and the acid will soak into the leather too slowly and create an inferior end product. Keep your leather at 150F while you prepare the stearic acid.
I also use the toaster oven to dry my leather. The dial is cranked up a little higher, door propped open, and a fan aimed at it to circulate the air. Just be sure to keep it under 150F.
Step 3: Fill your melting container with stearic acid, place on your heat source. Melt the stearic acid and then turn off the heat. Allow it to cool to 150F, +/- 5F.
Step 4: Immerse your preheated leather project into the stearic acid. Observe for bubbling as the leather soaks up the acid.
Step 5: When bubbling ends, turn the burner up to high. When the acid temperature nears ~200F, remove the pot from the heat.
Step 6: Allow the pot of stearic acid with your project immersed, to cool to about 145F. Remove your leather item.
Step 7: Immediately begin wiping off excess stearic acid from the leather with a paper towel or rag. Work quickly, as the stearic acid will begin to haze in less than a minute. You have a brief window of time to make any adjustments to shape as well.
Step 8: Allow the leather item to cool. I sometimes place the item in the freezer for ten minutes, or outside in cold weather.
Step 8: Once cool, the leather will be fully hardened. Finish edges by sanding from 220 up to about 3000 grit. After sanding, use dye to match the edge color to the rest of the piece. Rub briskly with canvas to buff. Then soften a bit of beeswax over a flame, run it over the edge, and buff again with canvas. This process results in a beautiful, durable, high gloss finish. The entire surface of the item can be buffed with canvas as well, to give added gloss.
Additional notes when working with X1
I use a belt sander for the early stages of edge finishing. You’ll find that sandpaper very quickly gets loaded with stearic acid and leather, and I strongly recommend a belt dressing device to get much more use out of your belts.
The flesh side of X1 leather will also burnish well, with no compound needed. Obviously, since the surface is far coarser, it will need more sanding at a coarser grit to begin, but polishes up beautifully.
Do not use a heat gun to soak up excess stearic acid after hardening as was mentioned in the original article. This will leave an inferior, chalky finish. Instead, repeat the immersion in stearic acid. Bring the acid up to 190-200F just briefly, and remove the leather. Wipe off excess thoroughly, to avoid pooling.
It’s difficult to adhere anything to stearic acid treated leather, but I have been successful using coad to glue snake skin to a hardened bracelet. This is a mixture of 50/50 pine rosin and beeswax and is easy to make at home. Google will yield plenty of methods.
X1 leather will take up dye to a limited degree. This is useful for covering scratches or redoing edges.
Layers of leather can be glued and stitched together to greatly increase thickness. These pieces should be given extra time to preheat and extra time to soak up the stearic acid. I also recommend raising the temperature much more slowly, to ensure that the thermal hardening effect is as uniform as possible, throughout the thickness of the leather.
If the leather is intended to be shaped around a rigid form, then wet-forming the piece prior to hardening is often unnecessary and can be skipped entirely. Since the leather remains pliable for a few minutes after removal from the stearic acid bath, that time can be used to form the leather around the desired shape before final hardening occurs. This can be done by simply holding it with the hands, suggesting the shape using blunt tools, wrapping with plastic wrap, vacuum sealing, or other methods. Keep in mind that the finish may be ruined by attempting to alter the shape of the piece while it’s too cool. If extra time is needed for shaping after hardening, remove the leather from the stearic acid bath while it’s a little warmer than you usually might, to allow longer working times.
The most common mistake I’ve been seeing in feedback from others attempting the technique, is a failure to follow the temperatures and times recommended. Understand that thinner leathers and larger pieces will remain somewhat flexible. The most rigid items are those made from 10 oz leather or thicker, and kept in small pieces or made as cases or containers, lending stability due to their geometry.
I’ll update and add to the troubleshooting section as I receive feedback. I also plan to write another article with new developments on the X1 technique, including torture testing with arrows and bullets, comparison with kydex and sheet steel, and others.
Following are photos of a few different items I’ve finished since developing this method. Thanks for reading!